Chem 4030/5260 Lecture Notes etc 2009

Charge Transfer Spectra Summary 

Notes on Colour - #1  

Notes on Colour - #2 

trans- [Ru(H2O)4Cl2]+ LMCT Analysis

Week 1- - Introduction to symmetry elements, operators, point groups; Required reading Chapters 2 and 3 of Lever, 1968


Week 2- - Direct products; reducible representations; orbital symmetries


Week 3- - application to determining infrared and Raman vibrations; Symmetry in Metal-ligand bonding; exercises in point group recognition; initial creation of MO diagrams


Week 4 - - MO diagrams, transitions and selection rules, for LMCT transitions in monochloro, dichloro and tetrachloro aquo ruthenium(III), low spin d6 systems- general principles


Week 5 etc will be updated depending on progress


Week 6 - 1st assignment due AND Mid-Term exam. Wed. April 8th, 2009


Week 7 -


Week 8-


Week 9


Week 10


Week 11, May 13; 2nd Assignment due


Assignments #1 due April 8th 2009.


EXAMINATION Final ..to be announced; 2nd Assignment due last day of term


Good Luck and Enjoy



All of the above applies to both Chem4030 and Chem5260 students BUT more depth will be demanded/expected of the Chem5260 students, and the assignments will be more demanding.